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KER 828 MSDS
 

KUMHO P&B CHEMICALS, INC.

Material Safety Data Sheet

KER Epoxy Resins

KER 828

Date: 01 June,1999
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY

·Product name : KER 828
·Product Code : L123A
·Product type : RESIN LIQUID
·Supplier : Kumho P&B Chemicals, Inc.
·Address : Korea
·Contact numbers : 82-2-6303-0114
·Emergency telephone number : 82-2-6303-0114
·Other information : http://www.kpb.co.kr
2. C0MPOSITION/INFORMATION ON INGREDIENTS

Substance chemical family:
Reaction product of bisphenol A and epichlorohydrin

CAS number:

25068-38-6

Other information:

Liquid epoxy resin

3. HAZARDS IDENTIFICATION

Human health hazards:
Irritating to eyes and skin. May cause sensitization by skin contact.

Safety hazards:

Not classified as flammable but will burn.

Environmental hazards:

Toxic to aquatic organisms.
May cause long term adverse effects in the aquatic environment.

4. FIRST AID MEASURES

Symptoms and effects:

Irritation of the skin and eyes

First Aid - Inhalation:

No specific measures.

First Aid - Skin:

DO NOT DELAY. Remove contaminated clothing. Wash skin with water using soap if available. If persistent irritation occurs, obtain medical attention.

First Aid - Eye:

DO NOT DELAY. Flush eye with water. If persistent irritation occurs, obtain medical attention.

First Aid - Ingestion:

Do not induce vomiting. In the unlikely event of ingestion, obtain medical attention immediately

Advice to physicians:

If skin sensitization has developed and a causal relationship has been confirmed further exposure should not be allowed.

5. FIRE FIGHTING MEASURES

Specific hazards:

Not classified as flammable but will burn.

Carbon monoxide may be evolved if incomplete combustion occurs.

Extinguishing media - small fires:

Dry chemical powder, carbon dioxide, foam, water spray or fog,sand or earth.

Extinguishing media - large fires:

Foam, water spray or fog.

Unsuitable extinguishing media:

Water in a jet.

Protective equipment:

Full protective clothing and self-contained breathing apparatus.

Other Information:

Keep adjacent containers cool by spraying with water.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions:

Avoid contact with skin, eyes and clothing.

Personal protection:

Wear protective clothing specified for normal operations (see Section 8).

Environmental precautions:

Prevent contamination of soil and water.

Prevent from spreading or entering into drains, ditches or rivers by using sand, earth, or other appropriate barriers.

If material enters drains, it should be pumped out into an open vessel.

Emergency services may need to be called to assist in this operation.

Clean-up methods - small spillage:

Absorb or contain liquid with sand, earth or spill control material. Shovel up and place in a labeled, sealable container for subsequent safe disposal.

Scrub contaminated surfaces with a detergent solution.

Retain washings as contaminated waste. Put leaking containers in a labeled drum or overdrum

Clean-up methods - large spillage:

Transfer to a labeled container for product recovery or safe disposal.

Otherwise treat as for small spillage.

Other information:

See Section 13 for information on disposal.

7. HANDLING AND STORAGE

Handling:

Avoid contact with skin, eyes and clothing.

Storage:

Keep container tightly closed and dry. Palletized loads should be stacked to a maximum of 4 high.

Storage temperatures:

Ambient.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational exposure standards:

None established.

Respiratory protection:

Not normally required.

In a confined space, wear half mask respirator with organic vapor cartridge and built-in particulate filter NPF 20 (gas only).

If product is applied by spraying, wear self-contained breathing apparatus.

Hand protection:

Nitrile rubber gloves or butyl rubber gloves, gauntlet type.

Eye protection:

Monogoggles.

Body protection:

Standard issue work clothes.

Safety boots - chemical resistant without lace holes.

9. PHYSICAL AND CHEMICAL

Physical state:

Colour:

Odour:

pH:

Boiling point:

Vapor pressure

Density:

Dynamic viscosity:

Electrical conductivity:

Flash point:

Auto-ignition temperature:

Solubility in water:

n-octanol/water partition
coefficient:

Liquid

Pale yellow

Slight

circa 7

> 200¡É.

< 0.01 Pa @ 20 °C

1160 kg/m3 @ 25 °C

12-14 Pa.s @ 25 °C

1150 pS/m @ 22 °C

> 200¡É (PMCC)

> 300 °C

circa 0.009 kg/m3 @ 23 °C

log Pow > 3

10. STABILITY/REACTIVITY

Stability:

Stable under normal use conditions. Reacts with strong oxidizing agents. Polymerizes exothermically with amines, mercaptans and Lewis acids at ambient temperature and above.

Polymerizes in contact with caustic soda. Reacts exothermically with bases (eg caustic soda), ammonia, primary and secondary amines, alcohols and acids.

Conditions to avoid:

Caustic soda can induce a vigorous polymerization at temperatures around 200 °C.

Materials to avoid:

Strong oxidizing agents. Caustic soda.

Hazardous decomposition products:

Hazardous decomposition products are not expected to form during normal storage.

11. TOXICOLOGICAL INFORMATION

Basis for assessment:

Acute toxicity - oral:

Acute toxicity - dermal:

Eye irritation:

Skin irritation:

Respiratory irritation:

Skin sensitization:

Carcinogenicity:





Mutagenicity:
Information given is based on product data.

LD50 > 2000 mg/kg

LD50 > 2000 mg/kg

Irritant

Irritant

Not irritating

Skin sensitizer

A recent review of the available data by the International Agency for Research on Cancer (IARC), has concluded that DGEBPA is not classifiable as to its carcinogenicity

Positive in in vitro, but negative in in vivo assays.
12. ECOLOGICAL INFORMATION

Basis for assessment:


Mobility:

Persistence/degradability:

Bioaccumulation:

Acute toxicity - fish:

Sewage treatment:
Incomplete ecotoxicological data are available for this Substance.

Sinks in water.

Not readily biodegradable.

IHas the potential to bioaccumulate.

Toxic, 1 < LC50 ¡Â 10 mg/l.

Toxic, EC50 >1-10 mg/l, to organisms in sewage treatment plants.
13. DISPOSAL CONSIDERATIONS

Precautions:

See Section 8. Refer to Section 7 before handling the product or containers.

Waste disposal:

Recover or recycle if possible. Otherwise incineration or dispose to licensed disposal contractor.

Product disposal:

Recover or recycle if possible. Otherwise incineration or dispose to licensed disposal contractor.

Container disposal:

Drain container thoroughly. Rinse three times with suitable solvent. Treat rinsings as for product disposal. After draining, vent in a safe place away from sparks and fire. Send to drum recoverer or metal reclaimer.

Local legislation:

14. TRANSPORT INFORMATION

IADR/RID Class/Item:


ADR/RID Symbol:

ADR/RID Kemler Number:

ADR/RID Proper Shipping Name:


Local regulations:
Not dangerous for conveyance under UN, IMO and IATA/ICAO codes.

9/II(C)

Miscellaneous dangerous substances.

90
3082

Environmentally Hazardous Substance, Liquid, N.O.S (Epoxy Resin)
15. REGULATORY INFORMATION

EC Label name:


EC Classification:

EC Symbols:

EC Risk phrases:





EC Safety phrases:
















EINECS (EC):

EC Annex I number:

MITI (Japan):

TSCA (USA):

AICS (Australia):

DSL (Canada):

National legislation:
Epoxy resin (Number Average Molecular Weight < 700)

Irritant. Dangerous for the environment.

Xi,N

R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S24 Avoid contact with skin.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S28 After contact with skin; wash immediately with plenty of soap and water.

S37/39 Wear suitable gloves and eye/face protection.

S61 Avoid release to the environment. Refer to special instructions /Safety data sheets.

Polymer exempt

603-074-00-8

Listed

Listed

Listed

Listed

Listed

16. OTHER INFORMATION


Uses and restrictions:

Compositions for the building and civil engineering industries e.g. flooring compounds, adhesives, mortars and grouts, solvent free and high-solids coatings, laminating binders.

DISCLAIMER:


This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.