products > phenoe &derivatives > msds > bisphenol msds
 
BISPHENOL MSDS
 

Bisphenol - A

1. IDENTIFICATION OF THE SUBSTACE/PREPARATION AND COMPANY

Chemical Identity : Diphenyol propane
Common name : Bisphenol-A
Registration number
CAS No. : 80 - 05 -7
Product Type : Chemical intermediate

Supplier

Kumho P&B Chemical Co., Ltd.

144-14, Wolha-dong, Yochon. Cholla Namdo, Korea

Tel : (061) 685-688-3500

2. COMPOSITION/INFORMATION ON INGREDIENTS


Composition

High purity diphenyol propane (Bisphenol-A)

Information on Ingredients

dangerous substances % (m/m) Symbols Rsisk Phraese

Diphenyolpropane >99 R36

3. HAZARDS IDENTIFICATION

To man To the environmental
·Irritating to eyes ·Toxic to fish, aquatic invertebrates and algae
·Harmful to bacteria
·Moderate potential for bioaccumulation
4. FIRST AID MEASURES

Symptoms and effects

·Inhalation : Non-irritant ·Eye : irritant
·Skin : Slightly irritant ·Ingestion : Non-irritant

First aid

Inhalation Eye
·Remove to fresh air ·Flush eye liberally with water
·If rapid recovery does not occur,·If irritation persists,
obtain medical attention obtain medical attention

Skin Ingestion
·Remove contaminated clothing ·DO NOT INDUCE VOMITING
·Wash skin with water,·If symptoms appear,
using soap if available obtain medical attention

Advice to physicians

Treat symptomatically

No specific measures for health surveillance or medical management are recommended

5. FIRE - FIGHTING MEASURES

Extinguish media

SMALL FIRELARGE FIRE

·Carbone dioxide·foam
·Dry chemical powder·Water spray
·Foam
·Stand/Earth
·Use water as a spray

Hazards

·This product is not in the flammable range but will burn
·Carbon monoxide is possible where incomplete combustion occurs

Protective equipment

·Wear self-contained breathing appratus for a large fir

 

6. ACCIDENTAL RELEASE MEASURES

Leaks and spills

·Extinguish any naked flames
·all spillages should be cleared up quickly

Small spillage

·Sweep/shovel up and remove to a safe places for subsequent disposal
·Flush the contaminated area with plenty of water

Large spillage

·Transfer to a salvage drum/tank if possible, otherwise treat as for a small spillage

Personal protection

·Refer Section 8
·In the event of inhalation risk wear high efficiency dust respirator(NPF 1000)

7. HANDLING AND STORAGE

Handling

·Danger of dust explosion

·Maintain adequate ventilation

·Electrostatic charges may be generated during handling, e.g. when crushing, grinding and  sewing or emptying bags

·All equipment should be earthed, including funnels, chutes and drums

Storage

·Satisfactory : carbonb steel, stainless steel, aluminium, polyethylene and paper bags

·Unsatisfactory : cooper, bronze

Storage conditions

·Store in cool, dry conditions

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls

·Although no exposure limit has been established for this product, an exposure limit of 10  mg/m3 for nuisance dusts and 6 mg/m3 for respirable dusts should be observed.

Personal protection

·Respiratory : not normally required in the event of inhalation risk use with local exhaust ventilation
If this is not practical wear a general purpose dust respirator(NPF 7-10)

·Hand : PVC gloves

·Eye : chemical monogoggles

·Skin : standard issue work clothes chemical resistant safety boots without lace holes

9. PHYSICAL AND CHEMICAL PROPERITIES (typical values)

Appearance (20 °C) : powder

odour : Mild

pH :

Boiling point/range : 360 °C

Melting point : 156.5 °C

Flash point(CC) : 207 °C

Flammability : Not classified as flammable but will burn if ignited

Autoflammability : 570 °C

Explosive properties(limits) : LEL = 12g/m3(dust cloud)

Oxidising properties : None

Vapour pressure(170 °C) : 2.6Pa

Relative density(25 °C) : 1.17

Solubility

- In water : 0.1% m/m (25 °C)
- In other solvents : Various org. solvents

Partition coefficient

n-octanol/water : log Pow = 2.2

Relative vapour density (air=1)

Viscosity(160 °C) : 3.55mPa.s

Color : White

Relative molecular mass : 228

Specific conductivity :

10. STABILITY AND REACTIVITY

Stability

·Stable under normal conditions at ambient temperature
·Can function as antioxidant

Conditions to avoid

·Decomposes above 11 mbar pressure when heated above 220 °C

Materials to avoid

·Readily undergoes condensation reactions

Hazardous decomposition products

11. TOXICOLOGICAL INFORMATION

Acute toxicity

·Oral(rat) LD : > 2000mg/kg
·Dermal(rabbit) LD : > 2000mg/kg
·Inhalation(rat) LC :

Irritation

·Skin : Slight
·Eyes : Moderate
·Respiratory :

Sensitisation

·Not a skin sensitizer

Other toxicological effects

·There is no conclusive evidence for carcinogenic or mutagenic(direct or indirect) potential  not teratogenic following oral administration; foatotoxicity and reproductive effects are only  observed at maternally toxic doses

12. ECOLOGICAL INFORMATION

Ecotoxicity

·Fish LC (96h) : 3.9 mg/L
·Daphnia (water fiea) EC (48h) : 3.9 mg/L
·Algae EC (96h) : 2.5 mg/L
·Bacteria EC ( 8h) : 55 mg/L

Persistence

 Degradation

·Biotic(5 days) : inherently biodegradable
·Abiotic :

Bioaccumulation : moderate potential

13. DISPOSAL CONSIDERATIONS

·Disposal : dispose to incinerator
·Classification
14. OTHER INFORMATION

Uses and restrictions

  Application

·raw material in preparation of epoxy resins and polycarbonate resin manufacture


SDS distribution

·It is recommended that the handling and safety information presented in this data sheet be passed on in an appropriata format, to your customers and handlers


History

Edition Number Date of Issue

1 July 1, 1994